ZnO nanoparticles coated and stearic acid modified superhydrophobic chitosan film for self-cleaning and oil–water separation

Abstract

The aim of this study was to prepare superhydrophobic chitosan films using a ZnO nanoparticle coating and stearic acid hydrophobic modification. A 1 % concentration of ZnO nanoparticles and a 1 % concentration of stearic acid generated a superhydrophobic film with the largest contact angle (WCA) of 156°, which was attributed to the synergy of micro/nano-level hierarchical structure and low surface energy modification. The superhydrophobic film showed better stability to acid, alkali, heat, and UV irradiation than a neat chitosan film and a reduction in light transmittance of 14.4 % at 354 nm. The superhydrophobic chitosan film also showed excellent self-cleaning and oil–water separation performance. Our findings will expand the application of chitosan films in food packaging, outdoor self-cleaning materials and oil–water separations.