Abstract
在水热条件下, 利用锌离子与2种有机配体合成出1个结构新颖的金属有机骨架化合物[Zn 2 (BPDC)(IN) 2 ] (H 2 BPDC=4,4'-联苯二羧酸; HIN=异烟酸), 并通过单晶X射线衍射、红外光谱、热重分析和荧光光谱等对该化合物进行了表征. 结果表明, 该化合物结构中Zn离子与BPDC的羧基形成双核金属次级结构单元[Zn 2 (-CO 2 ) 2 (IN) 2 ], 相邻次级结构单元通过IN配离子连接形成[Zn 2 (-CO 2 ) 2 (IN) 2 ] ∞ 二维层面, 相邻的二维层通过BPDC相互连接形成具有三重互穿的简单格子拓扑结构. 该化合物表现出良好的荧光性质.
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