Abstract
The present work reports the synthesis of two new zinc(II) complexes based on the 2-acetylfuranisonicotinichydrazone ligand (HL). The structure of the hydrazone and [ZnCl2(HL)]·MeOH (1) and [Zn(L)2] (2) have been elucidated by single-crystal X-ray diffraction method, physicochemical, and spectroscopic techniques. The hydrazone is a bidentate ligand, forming two new mononuclear complexes with zinc(II). Non-covalent interactions in the structures of the compounds were evaluated with Hirshfeld surface analysis, which showed the presence of hydrogen bonds in HL and 1 and also a π···π stacking interaction in 1. The antimycobacterial potentials of the compounds were tested against tuberculous and non-tuberculous mycobacteria strains.
Published Version
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