Zirconium-containing UiO-66 as an efficient and reusable catalyst for transesterification of triglyceride with methanol

Abstract

Zirconium-based MOFs of the UiO family have attracted considerable attention due to their high thermal, chemical and mechanical stability. With the aim of further exploring the applications of zirconium-based UiO-66 in acid-catalyzed reactions and elucidating the effects of the defects in UiO-66 materials on their catalytic performances, in this work, a series of zirconium-containing UiO-66 samples were synthesized by varying the synthesis temperatures and BDC/Zr (terephthalic acid/ZrCl4) ratios in the synthesis system. The synthesized UiO-66 samples were characterized by X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM), thermogravimetrical analysis (TGA), temperature-programmed desorption of NH3 (NH3-TPD). Their catalytic performances were investigated in transesterification of tributyrin and soybean oil with methanol. The results showed that UiO-66 samples with different amounts of defects could be successfully prepared by varying the synthesis temperatures and/or the BDC/Zr ratios used in the synthesis system. The catalytic activities of the UiO-66 materials greatly depended on their linker defects and enhanced with the increase of the defect amount. The UiO-66 was an efficient catalyst for transesterification of tributyrin and soybean oil with methanol under mild reaction conditions and its catalytic activity was comparable to other solid acid catalysts reported in the literatures. The UiO-66 catalyst was relatively stable and could be reused.