Abstract
The carbon-carbon bond formation reactions of diynes with EtMgBr can be catalysed by Cp 2ZrCl 2. The final products, magnesiated enynes, readily undergo stereoisomerization to give a mixture of (E) and (Z) isomers. The stoichiometric reaction of diynes with ethylene zirconocene gives zirconacyclopentenes with alkynyl substituents in the α position with high regioselectivities.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
