Zinc-rich polyester powder coatings with iron Phosphide: Lower zinc content and higher corrosion resistance

Abstract

Many conductive fillers such as carbon black, carbon nanotube and graphene, have been developed to reduce zinc content for zinc-rich coatings, but very few of them could reduce zinc content by 10 % while maintaining the original corrosion protection ability. The carbon-based conductive additives have the issue of corrosion promotion after cathodic protection. In this study, low-cost iron based conductive additive, iron phosphide was used to reduce zinc content in environmentally friendly zinc-rich polyester powder coatings. We investigated the anti-corrosive performance of the prepared coatings by open circuit potential, electrochemical impedance spectroscopy measurements and neutral salt spray tests. The corrosion products were analyzed with Raman spectroscopy, X-ray diffraction and scanning electron microscopy equipped with energy dispersive X-ray spectroscopy. It was found that iron phosphide, due to its conductive nature, inert chemistry, activation function and barrier effect of the lamellar shape, can establish cathodic protection at a low zinc content of 45 wt% with an active protection period of 20 days. It can replace 10 wt% of zinc in 75 wt% zinc-rich polyester powder coatings while maintaining the original cathodic protection ability, as long as 86 days for a 40 μm film. In addition, iron phosphide can significantly inhibit localized corrosion and decrease corrosion creepage by about 20 % during 2500 h salt spray tests. Moreover, a possible corrosion protection mechanism for iron phosphide in zinc-rich polyester coatings was proposed.