Abstract
AbstractTwo new metal complexes [Zn(L1)]n (1) and [Cd3(L2)2Cl2(H2O)6]n (2) (H2L1 = 1,5‐bis(tetrazol‐5‐yl)‐3‐oxapentane, H2L2 = bis(tetrazol‐5‐yl)methane) have been synthesized and characterized by elemental analysis, IR spectroscopy and single‐crystal X‐ray diffraction analysis. Complex 1 was a 2‐D sheet constructed by L1 and Zn(II) center, further assembled to form a three‐dimensional (3‐D) supramolecular networks through weak hydrogen‐bonding interactions. In the complex 2, there were two unequivalent Cd(II) centers, and some of ligands L2 adopted chelate coordination mode, and others adopted bridge coordination mode linking the Cd1 center and simultaneously bridging the Cd2 center, the Cl‐ anions adopted μ2 bridging mode, ligands L2 and the Cl‐ anions linked the Cd(II) centers to form a 3‐D supramolecular networks.
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