Abstract
In this letter, the authors directly observed the zinc-blende (ZB) ZnO core in the initial formation of wurtzite (WZ) ZnO tetrapods. The formation of the wurtzite (011¯3) twined nanowires is proposed based on the ZB core. Simple bonding density calculation shows that the wurtzite nanowires with {011¯0} side surfaces have the lowest surface energy. A favorable choice of WZ phase over ZB when forming nanostructures is likely to be a result of surface energy minimization. This could be the reason that ZnS nanowires take WZ rather than ZB.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.