Abstract
The zero-order desorption kinetics is described for adsorbate systems in which three phases are in equilibrium and first-order desorption kinetics is assumed for the desorption from the topmost phase. The calculated results represent typical features of the observed zero-order desorption spectra. The possibility of specifying the phase boundaries from the thermal or isothermal desorption spectra is proposed. The relationship between the thermal or isothermal desorption processes and trajectories in the phase diagram is also discussed.
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