Abstract
Abstract The preparation and characterization of some Ni(0) and Pt(0) complexes of 5,5-dimethyl-2-phenoxy-1,3,2-dioxaphosphorinane is reported. This phosphite, which contains a single six-membered ring, displays donor-acceptor properties intermediate to P(OCH2)3CR and trialkyl or triaryl phosphites. The conformation of the ligand in the complexed form is proposed to be a chair ring with an axial phenoxy group.
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