Abstract
AbstractOn the basis of the crystal field theory the energy matrices of a d5 ion in Cs (or C2) symmetry are derived, which are applicable to all orthorhombic and tetragonal symmetries. Using the perturbation theory the analytical expressions connecting the zero‐field splitting parameters with the crystal field parameters are obtained for a 6S‐state ion in arbitrary symmetry. It is shown that the zero‐field splitting of Mn2+ on Ca(II) sites in Ca5(PO4)3F, possessing Cs point symmetry, can be reasonably understood by the spin–orbit coupling mechanism, and that the d–d transitions can be interpreted well by the crystal field model proposed by Zhao et al.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
