Zero-dimensional analysis of the effect of water vapor on reducing electrons in the plasma sheath

Abstract

In this study, an air-water vapor ionization reaction model is developed within the quantum-kinetic (Q–K) model of the direct simulation Monte Carlo method to investigate the detailed mechanism of how water vapor reduces electrons. The zero-dimensional simulations of a typical non-equilibrium flow field downstream of a normal shock are designed, where the electron number density decreases by two orders of magnitude due to water vapor. We conclude that the introduction of water vapor reduces the mole fractions of oxygen atoms and nitrogen atoms through five pairs of reactions and enhances the reverse nitric oxide associative ionization reaction, leading to electron consumption. The phenomena and corresponding mechanisms under varying mole fractions of water vapor, air temperatures, and water vapor temperatures are investigated. Based on the mechanisms, we propose that the addition of hydrogen ions could improve the water's mitigation effect, which is then proven to be able to reduce the electron number density by another two orders of magnitude, not only at high air temperatures but also at lower air temperatures or lower mass injection rates.