Abstract
Alternative biobased bisphenols from lignocellulosic biomass are not only favorable to reduce the environmental impact of current petroleum-derived plastics, but they can be simultaneously beneficial for health issues related to bisphenol A (BPA). Additionally, conventional BPA synthesis entails a large excess of unrecoverable homogeneous acid catalyst (e.g., HCl) or unrecyclable thermolabile sulfonated resins. In this report, zeolites are proposed as recoverable and thermally stable solid acids for the Brønsted-acid-catalyzed condensation between 4-methylguaiacol and formaldehyde to selectively produce renewable bisphenols. It is found that the Brønsted-acid-site density plays a pivotal role for catalyst performance. In particular, the cheap and environmentally friendly FAU 40 exhibits outstanding activity (turnover frequency of 496 h-1 ) and selectivity (>95 %), outperforming even the best benchmark catalyst. Additionally, the zeolite can be easily recycled without activity loss after regeneration by coke burn-off. The catalytic zeolite system also seems very promising for other lignin-derived alkylphenols, alkylguaiacols, and alkylsyringols.
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