Abstract

A two-step method was used to load TiO2 on a cement matrix, and zeolite was chosen as intermediate support. TiO2@Zeolite composite coated photocatalytic cement-based material (PCM) was prepared. Some advanced characterization technologies including X-ray diffraction (XRD), scanning electronic microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and BET specific surface area (SSA) test were applied to characterize the physicochemical properties of as-prepared PCM. Photocatalytic degradation of trichloroacetamide (TCAcAm) was conducted to evaluate its photocatalytic efficiency. Results show that TiO2@Zeolite composite can improve the adsorption ability of PCM and TiO2 particles were dispersed on the surface of PCM homogeneously providing abundant active sites for photocatalytic reactions. Moreover, TiO2@Zeolite composite can reduce the negative effect of cement on TiO2. The synergetic effect of TiO2@Zeolite composite can remarkably improve the photocatalytic degradation rate, reaching up to 97.8%. TiO2@Zeolite composite coated PCM holds great promise to eliminate water pollution.

Highlights

  • Nowadays, water pollution is a big environmental health concern worldwide as multiple harmful substances such as antibiotics, microbes, and dyestuffs are detected in drinking water

  • TiO2@Zeolite Composite Coated photocatalytic cementbased material (PCM) Fabrication 22 g cement and 8.8 g water were mixed for 5 min by a mixer, and the fresh cement paste was casted in a round mold with a diameter of 50 mm and a height of 8 mm

  • The samples were labeled as n-TZ-m-PCM, where n stands for the final thermal treatment temperature, m% stands for the mass ratio of

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Summary

INTRODUCTION

Water pollution is a big environmental health concern worldwide as multiple harmful substances such as antibiotics, microbes, and dyestuffs are detected in drinking water. Zeolite/TiO2 Photocatalytic Cement-Based Composite the derived nitrogen-disinfection by-products (N-DBPs) are proved to be more toxic than C-DBPs (Chu et al, 2012). Degradation of trichloroacetamide (TCAcAm) was conducted to evaluate the purification effect of the as-prepared TiO2@zeolite composite coated PCM. TiO2@Zeolite Composite Coated PCM Fabrication 22 g cement and 8.8 g water were mixed for 5 min by a mixer, and the fresh cement paste was casted in a round mold with a diameter of 50 mm and a height of 8 mm. The samples were labeled as n-TZ-m-PCM, where n stands for the final thermal treatment temperature, m% stands for the mass ratio of TABLE 1 | Chemical composition of natural zeolite/%. Gas chromatography-mass spectrometry (GC/MS) was used to measure the TCAcAm in the upper extractant solution

RESULTS AND DISCUSSION
CONCLUSION
DATA AVAILABILITY STATEMENT

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