Abstract

Zeise's salt, anhydrous and monohydrate, has been prepared by a new method similar to the original method used by Zeise. The infrared and laser Raman spectra of the anhydrous Zeise's salt together with the infrared spectra of the deutero and bromo analogs, are reported and discussed. The vibrational spectra are interpreted in terms of a cyclopropane-like ring structure, obtained by the insertion of the platinum atom into the double bond.

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