Abstract
In the structure of the title compound, [Fe(C5H5)(C14H10N)], the unsubstituted cyclopentadiene (Cp) ring is disordered over two positions, with site-occupancy factors 0.76 (2) and 0.24 (2). The dihedral angles between the substituted Cp ring and the major and the minor components of the disordered ring are 0.9 (5) and 6(2)°, repectively. The plane of the acrylonitrile unit makes dihedral angles of 6.1 (18) and 6.5 (4)° with the substituted Cp ring and the phenyl ring planes, respectively.
Highlights
In the structure of the title compound, [Fe(C5H5)(C14H10N)], the unsubstituted cyclopentadiene (Cp) ring is disordered over two positions, with site-occupancy factors 0.76 (2) and 0.24 (2)
The dihedral angles between the substituted Cp ring and the major and the minor components of the disordered ring are 0.9 (5) and 6(2), repectively
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SJ2497)
Summary
The dihedral angles between the substituted Cp ring and the major and the minor components of the disordered ring are 0.9 (5) and 6(2), repectively. The plane of the acrylonitrile unit makes dihedral angles of 6.1 (18) and 6.5 (4) with the substituted Cp ring and the phenyl ring planes, respectively. Related literature For background to the chemistry of ferrocene, see: Long (1995); Roberto et al (2000); Togni & Hayashi (1995). For the stuctures of ferrocene derivatives, see: Base et al (2002); Hess et al (1999). Crystal data [Fe(C5H5)(C14H10N)] Mr = 313.17 Monoclinic, P21=c a = 6.8255 (14) Ab = 11.795 (2) Ac = 19.939 (4) A = 106.786 (16)
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