(Z)-3-(4-Chlorophenyl)-2-(2-phenylcyclohex-2-en-1-ylimino)thiazolidin-4-one

Chin Wei Ooi,Alagusundaram Ponnuswamy,Murugan Sathishkumar,Hoong-Kun Fun,Ching Kheng Quah

doi:10.1107/s1600536812024294

Abstract

The title compound, C21H19ClN2OS, exists in a cis conformation with respect to the N=C bond [1.2608 (13) Å]. The cyclohexene ring adopts a distorted half-chair conformation. The thiazolidine ring is close to being planar (r.m.s. deviation = 0.057 Å) and makes dihedral angles of 62.92 (6) and 56.32 (6)°, respectively, with the benzene ring and the chloro-substituted benzene ring. The dihedral angle between the benzene ring and the chloro-substituted benzene ring is 72.91 (6)°. In the crystal, molecules are linked by C—H⋯O and C—H⋯N hydrogen bonds into undulating sheets lying parallel to the bc plane. The crystal is further consolidated by C—H⋯π interactions.

Highlights

The title compound, C21H19ClN2OS, exists in a cis conformation with respect to the N C bond [1.2608 (13) Å]
Molecules are linked by C—H O
For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986)

Summary

Data collection

The title compound, C21H19ClN2OS, exists in a cis conformation with respect to the N C bond [1.2608 (13) Å]. The cyclohexene ring adopts a distorted half-chair conformation. 56.32 (6) , respectively, with the benzene ring and the chloro-substituted benzene ring. The dihedral angle between the benzene ring and the chloro-substituted benzene ring is. Molecules are linked by C—H O and C—H N hydrogen bonds into undulating sheets lying parallel to the bc plane.

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Special details