Abstract

In the title compound, C10H9ClN4OS, an intra­molecular N—H⋯O hydrogen-bonding inter­action and an N—H⋯N inter­action generate ring motifs [graph sets S(6) and S(5), respectively]. In the crystal, mol­ecules form a chain through N—H⋯O hydrogen bonds, and these are extended by N—H⋯S hydrogen-bonding inter­actions into an infinite three-dimensional network. The crystal structure also exhibits weak C—H⋯π inter­actions.

Highlights

  • H O hydrogen-bonding interaction and an N—H N interaction generate ring motifs [graph sets S(6) and S(5), respectively]

  • Cg2 is the centroid of the C1–C6 ring

  • Symmetry codes: (i) −x+1, y+1/2, −z+3/2; (ii) x−1/2, −y+1/2, −z+2; (iii) x−1/2, −y+3/2, −z+2

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Summary

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School of Chemical Sciences, Universiti Sains Malaysia, Minden, Penang, Malaysia, Faculty of Science, Sabha University, Libya, cDepartment of Chemistry, International University of Africa, Khartoum, Sudan, , and dX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia

Bruker APEXII CCD diffractometer
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