Yttrium effect on 475 °C brittleness of Fe–13Cr–6Al–2Mo-0.5Nb-0.15Zr alloy

Abstract

The effect of yttrium on the 475 °C brittleness and microstructure stability of Fe–13Cr–6Al–2Mo-0.5Nb-0.15Zr alloy after long-term aging at 475 °C has been investigated. At the early stage of aging, the nanoscale metastable transition phase precipitates in large quantities. After aging for 10,000 h, the nanophase in the Y-free alloy has completely disappeared, and only a great deal of granular Laves phases are left, while a large number of nanoscale phases still exist in the grain of Y-containing alloys. This is because the addition of yttrium combines with vacancies, hinders the diffusion of Laves phase-forming elements, and has the result that the transformation of nanoscale phases Fe2(Mo0.3Nb0.7)Al to Laves phase is inhibited during the aging process of the Y-containing alloys. During aging, precipitation-free zones (PFZ) are formed in the surrounding area where the Laves phase and grain boundaries exist. The elongation of Y-containing alloys decreases with yttrium content, but it is still higher than that of Y-free alloy. The addition of yttrium improves the aging plasticity and weakens the degree of 475 °C brittleness of the alloy, and the effectiveness is diminished with the yttrium. This plays a key role in the further study of Fe–Cr–Al alloys for fuel cladding materials.