Yttrium and rare-earth modified lithium orthoborates: Glass formation and vibrational activity

Abstract

Glass formation and structure-property relations were explored in highly modified borate glasses containing high loads of rare-earth elements, whose crystalline analogues display a trigonal to tetrahedral borate phase transition (BO33− → BØ2O23−, where Ø and O− indicate bridging and non-bridging oxygen atoms). The resulting borate networks are completely depolymerized, where borate anions are crosslinked to rare-earth and modifier cations via ionic bonds. The borate structure was found to be based on a single structural unit, BO33− triangles, whose fundamental vibrations are all active in both the Raman and infrared. The local environment of the rare-earth ions in orthoborate glasses was studied with far infrared spectroscopy and, in some cases, by using terbium as a probe ion. A linear correlation was obtained between the effective force constant in the far infrared and the field strength of the rare-earth cation.