Yttrium and Lithium Complexes with Diamidophosphane Ligand Bearing 2,1,3-Benzothiazolyl Substituent: Polydentate Complexation and Reversible NH–PH Tautomery

Abstract

Deprotonation of a bis(amino)phosphane H2L = PhP(HNBtd)2 bearing a heterocyclic Btd = 2,1,3-benzothiadiazol-4-yl substituents at nitrogen atoms by silylamides LiNTms2 and Y(NTms2)3 (Tms = trimethylsilylamide) results in lithium and yttrium complexes with the deprotonated HL– and L2– forms as κ2-N and κ4-N chelating ligands. A binuclear complex [LiHL]2 was crystallized from Et2O, and was shown to reversibly dissociate in thf (tetrahydrofuran) with the NH(soln)–PH(crystal) tautomeric shift; the compound [Li2L] was spectroscopically characterized. Yttrium readily forms stable bis-ligand complexes [YL2]– and [YL(HL)]. In the latter, the H atom in HL resides on phosphorus; the coordination sphere remains accessible to another ligands, and it was crystallized as [{YL(HL)}2(µ-dioxane)] species (YN8O coordination). In the former complex, the coordination sphere was saturated (YN8) by closer bound ligands; it was crystallized as a salt with [Li(thf)4]+. The monoligand complex could not be cleanly obtained in a 1:1 reaction of H2L and Y(NTms2)3, and was only crystallographically characterized as a dimer [YL(NTms)2]2. Partial oxidation of the central P atom with the formation of phosphine-oxide ligands PhP(O)(NBtd)2– was observed. They co-crystallize in the same position as non-oxidized ligands in [YL2]– and [YL(NTms2)]2 species and participate in bonding between two units in the latter. TD-DFT calculations reveal that main transitions in the visible region of electronic spectra correspond to the charge transfer bands mostly associated with the orbitals located on Btd fragments.