Yellow Emissive CsCu2I3 Nanocrystals Induced by Mn2+ for High-Resolution X-ray Imaging.

Abstract

Recently, low-dimensional copper(I)-based perovskite or derivatives have gained extensive attention in scintillator applications because of their environmental friendliness and good stabilities. However, the unsatisfactory scintillation performance and complex fabrication processes hindered their practical applications. Herein, efficient yellow emissive CsCu2I3 nanocrystals (NCs) were successfully prepared via a simple Mn2+-assisted hot-injection method. The added Mn2+ effectively induced the phase transformation from Cs3Cu2I5 to CsCu2I3, leading to the preparation of single-phase CsCu2I3 NCs with few defects and a high fluorescence performance. The as-prepared "optimal CsCu2I3 NCs" exhibited superior photoluminescence (PL) performance with a record-high PL quantum yield (PLQY) of 61.9%. The excellent fluorescence originated from the radiative recombination of strongly localized one-dimension (1D) self-trapped excitons (STEs), which was systematically investigated via the wavelength-dependent PL excitation, PL emission, and temperature-dependent PL spectra. These CsCu2I3 NCs also exhibited outstanding X-ray scintillation properties with a high light yield (32000 photons MeV-1) and an ultralow detection limit (80.2 nGyair s-1). Eventually, the CsCu2I3 NCs scintillator film achieved an ultrahigh (16.6 lp mm-1) spatial resolution in X-ray imaging. The CsCu2I3 NCs also exhibited good stabilities against X-ray irradiation, heat, and environmental storage, indicating their great application potential in flexible X-ray detection and imaging.