Yb[N(SO 2C 8F 17) 2] 3-catalyzed allylation of 1,3-dicarbonyl compounds with allylic alcohols in a fluorous biphase system

Abstract

Allylation of 1,3-dicarbonyl compounds with allylic alcohols was successfully accomplished using rare earth metal (III) bis(perfluorooctanesulfonyl)imide [RE(NPf 2) 3, RE = La∼Lu] as catalysts in fluorous solvents. Ytterbium bis(perfluorooctanesulfonyl)imide [Yb(NPf 2) 3] catalyzes the high efficient reaction of allylation in fluorous solvents. By simple separation, fluorous phase containing only catalyst can be reused several times.