Abstract
AbstractThe phosphite triester (6), the O,O,O‐thiophosphate triester (7), and the phosphate triester (8) of methyl β‐d‐ribopyranoside were prepared. Crystal structures of 6 and 7 were determined by X‐ray diffraction. Quantum‐chemical calculations were performed on 6. They clearly demonstrate that the positive charge on phosphorus is relatively high. This high charge is a result of the strain in the ester moiety of 6.
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