X-ray peaks profile analysis, optical and cathodoluminescence investigations of cobalt-doped ZnO nanoparticles

Abstract

Effects of Co doping on the structural and optical properties of ZnO oxide nanoparticles (NPs) prepared by a solvothermal method are reported. X-ray diffraction examinations using Rietveld refinement confirms the hexagonal wurtzite symmetry ZnO phase nanostructure belonging to P63mc space group. No segregated secondary phases or Co rich clusters were detected. The X-ray diffraction peaks shifts towards higher angle gradually as the concentration of nominal Co content increases in ZnO. This shifting in peak position reflect that Co is well replaced Zn in ZnO matrix. With increasing the Co content to 3%, both lattice parameters a and c of the hexagonal ZnO tended to gradually decrease, suggesting substitutional doping of Co at the tetrahedral Zn2+sites. For Co loading of5%, these trends reversed and the lattice showed a gradual expansion, which is explained by additional interstitial incorporation of Co. The Williamson-Hall (W–H) method with various models i.e. uniform deformation model (UDM), uniform stress deformation model (USDM) and uniform deformation energy density model (UDEDM), as well as size-strain plot (SSP) method, and the morphological observations using transmission electron microscopy (TEM) image were used to evaluate the crystallite size as well as the lattice strain. Optical studies carried out by diffuse reflectance spectroscopy (DRS) indicated a decrease in the value of the band gap from 3.238 eV to 2.993 eV with increasing Co doping concentration. The obtained results are confirmed by cathodoluminescence technique.