X-ray design constraints forin situelectrochemical cells: importance of window material, electrolyte and X-ray wavelength

Abstract

The need to calculate X-ray absorption losses through window materials and electrolytes in electrochemical cells used forin situX-ray studies is highlighted. Calculations of the loss of beam intensity through Mylar windows of various thicknesses and at different wavelengths are carried out. Other window materials, such as polyethylene, polyimide (Kapton), polymethylmethacrylate (Perspex), polycarbonate (Lexan) and polyamide (Kevlar), are considered. Linear absorption coefficients and loss of intensity through different thicknesses of these materials at the CuKα wavelength are considered. Calculations of loss of intensity for a typical experimental case involving a Mylar cell window and a 1.029 MH2SO4electrolyte are presented.