X-ray Structures and Complete NMR Assignment by DFT Calculations of [Os(bpy)2(CO)Cl]PF6 and [Os(bpy)2(CO)H]PF6 Complexes

Abstract

The X-ray structures of [Os(bpy)2(CO)(Cl)][(PF6)] (1) and [Os(bpy)2(CO)(H)][(PF6)] (2) (where bpy = 2,2‘-bipyridine) have been solved. In complex 1, belonging to the C2/cspace group, the Cl- and CO...