Abstract
Abstract Two novel polypyrazolylborate complexes of beryllium, [Be{B(pz)4}2] (1) and [Be3(OH)3{HB(pz)3}3] (2), have been prepared in aqueous solution, and their X-ray crystal structures have been determined. Complex 1 contains a tetrahedral Be2+ with each ligand having bidentate coordination. In complex 2, each HB(pz)3− is attached to a cyclic [Be3(OH)3]3+ moiety by two Be-N coordination bonds and one OH-N hydrogen bond.
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