Abstract

The crystal and molecular structures of the title compounds were determined by x-ray diffractometric analysis. Torsion angles and puckering parameters are reported for both compounds. In 1 the 5α-cyano group influences the A-ring conformation. The carbonate ester 3 crystallizes in the monoclinic P2 1 space group with two molecules ( I and II) in the asymmetric unit. The D-ring conformation is to some extent different between I and II . ( Steroids 57:502–506, 1992)

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