Abstract
A complex experimental study of Cu(2p 3/2), Cu(2p 1/2) photoelectron and Kα1,2 and Lα1,2 X-ray emission spectra of copper in copper phthalocyanine CuPcH16 and its fluoro-substituted analog CuPcF16 is carried out. A charge transfer model is used to interpret the spectra. It is shown that Kα1 and Kα2 lines of the spindoublet of copper have a complex structure due to the processes of metal-to-ligand charge transfer. The role of a satellite in the formation of emission lines is revealed.
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