X-ray scattering by many-particle systems

Abstract

This paper reviews the treatment of high-frequency Thomson scattering in the non-relativistic and near-relativistic regimes with the primary purpose of understanding the nature of the frequency redistribution correction to the differential cross-section. This correction is generally represented by a factor involving the ratio ωα /ωβ of the scattered (α) to primary (β) frequencies of the radiation. In some formulae given in the literature, the ratio appears squared, in others it does not. In Compton scattering, the frequency change is generally understood to be due to the recoil of the particle as a result of energy and momentum conservation in the photon–electron system. In this case, the Klein–Nishina formula gives the redistribution factor as . In the case of scattering by a many-particle system, however, the frequency and momentum changes are no longer directly interdependent but depend also upon the properties of the medium, which are encoded in the dynamic structure factor. We show that the redistribution factor explicit in the quantum cross-section (that seen by a photon) is ωα /ωβ, which is not squared. Formulae for the many-body cross-section given in the literature, in which the factor is squared, can often be attributed to a different (classical) definition of the cross-section, though not all authors are explicit about which definition they are using. What is shown not to be true is that the structure factor simply gives the ratio of the many-electron to one-electron differential cross-sections, as is sometimes supposed. Mixing up the cross-section definitions can lead to errors when describing x-ray scattering. We illustrate the nature of the discrepancy by deriving the energy-integrated angular distributions, with first-order relativistic corrections, for classical and quantum scattering measurements, as well as the radiative opacity for photon diffusion in a Thomson-scattering medium, which is generally considered to be governed by quantum processes.