Abstract

The crystal structure of lanthanum orthovanadate LaVO4 has been refined by the Rietveld refinement of powder X-ray data. The structure is monoclinic, space group P21/n (a non-standard setting of P21/c No. 14), with a=7.0434(1) Å; b=7.2801(1) Å; c=6.7224(1) Å; β=104.864(1)°, V=332.51(9) Å3, Z=4, Dx=5.07 g cm−3. The present results are in good agreement with the single-crystal X-ray diffraction results.

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