Abstract
Abstract This account reviews recent development of in situ crystallographic study of reactive intermediates using the cryo-trapping method. Starting from the basic concept of a reaction cavity in a crystal, we succeeded in not only observing photoinduced reactive species such as radical, carbene, and nitrene but also establishing a unique approach, crystalline molecular flask, to observe labile species in chemical reactions in a crystal. On the basis of such a crystalline reaction field design, we successfully observed irreversible reactive intermediates in a crystal.
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