Abstract

The pseudobinary system PbSe-Bi2Se3 has been studied by x-ray diffraction using cleaved single-crystal specimens and powders, and the compositions of the layered compounds existing in this system have been refined. The monoclinic cell parameters of the compounds Pb5Bi6Se14 and Pb5Bi12Se23, belonging to the [(PbSe)5] m [(Bi2Se3)3] n homologous series, have been determined.

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