Abstract

PbTe–Bi2Te3alloys were studied by x-ray diffraction (XRD) and microstructural analysis. Single-crystal XRD studies of cleaved surfaces showed that the PbTe–Bi2Te3system contains an nPbTe · mBi2Te3homologous series of layered compounds with n= 1, 2 and m= 1–4. In addition to the known compounds PbBi2Te4and PbBi4Te7 , three new layered compounds with n/m 1 were identified in the PbTe–Bi2Te3system, in contrast to GeTe–Bi2Te3and GeTe–Sb2Te3 .

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