Abstract
Molten structures of some trivalent halides were investigated by high-temperature X-ray diffraction method. Shortranged structure of the melts, in which cation tends to be surrounded by six halide ions, was precisely determined from radial distribution function G(r). A first sharp diffraction peak corresponding to a medium-ranged structural order was detected in those melts. In the present work, correlation between the medium-ranged structural order and dynamic properties is discussed in view of the molecular dynamics simulation technique.
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