Abstract

Ternary clinopyroxenes have been synthesized in the plane Di-CaTs-En. The variation of their crystallographic parameters has allowed the development of three determinative grids, which utilize b-β, 2θ22¯1−2θ310 and 2θ330 −2θ202 respectively. These grids show significant differences in comparison with the previously proposed ones. Present results have been used to review some data on clinopyroxenes equilibria in the system CaO-MgO-Al2O3-SiO2 (CMAS) (Biggar 1969; Bruno and Facchinelli 1978; Herzberg 1978; O'Hara and Schairer 1963; Boyd 1969). In particular the petrogenic grid correlating P, T and CaTs content of clinopyroxenes in spinel-lherzolite assemblage (Herzberg 1978) has been revised, and consequently equilibrium temperatures rise by one hundred degrees.

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