Abstract
X-Ray analysis of the structure of the complex (1) formed between N-bromosuccinimide and the tertiary base 1,4-diazabicyclo[2.2.2]octane(DABCO)shows the compound to contain a nearly linear [175.1(2)°]N–Br–N bond with an exceptionally long bromine to DABCO distance [2.332(4)A]and a bromine to succinimido distance of 1.945(4)A; MNDO and ab initio SCF-MO calculations on the model system N-chlorosuccinimide + NH3show charge transfer to occur from both the halogen and the amine to the succinimido moiety upon complex formation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
