X-ray absorption multiple-scattering study of angle distribution in high-T c superconductors

Abstract

A new method, designed to perform data-analyis of X-ray absorption data and previously applied to molecular cases, has been used to investigate high- T c superconductros for the first time. This method includes properly multiple-scattering contributions to the EXAFS spectra. In this way, it is possible to derive unconventional structural information such as the angle distributions associated with the main scattering paths. We have analyzed well-known superconducting samples such as YBa 2Cu 3O ≈7 and Bi 2Sr 2CaCu 2O ≈8. In both cases, quantitative local structural information has been extracted form Cu K-edge EXAFS spectra by using a fitting procedure which performs the average of the multiple-scattering contributions. The dominant signal due to the inplane CuOCu angle distribution has been accurately studied taking proper account of the multiple-scattering signals due to the quasi-linear configurations. A good agreement with difraction results has been found. This application shows the capability of EXAFS to measure the local CuOCu angle distribution in this class of compounds.