X-ray absorption fine structure spectroscopy and photoluminescence study of multifunctional europium (III)-doped hydroxyapatite in the presence of cationic surfactant medium

Abstract

Europium-doped hydroxyapatite has attracted considerable scientific attention to smart drug delivery scaffold applications because of its biocompatible and traceable luminescence features. In this sense, to investigated the europium incorporation mechanism and photoluminescence properties in the presence of surfactant organic molecules the europium doped-hydroxyapatite samples were synthesized via co-precipitation with hexadecyl trimethylammonium bromide (CTAB) micelles mediated approach. Results of the X-ray absorption spectroscopy techniques (XANES and EXAFS) showed that Eu3+ ions were incorporated preferentially at the Ca (1) site with local charge compensating via oxygen interstitial ion for samples calcined under air at 450 °C/4 h °C. Europium(III) luminescence analysis suggested that Ca site symmetry became distorted in CTAB medium.