Wpływ rodzaju bazy olejowej na właściwości reologiczne ekologicznych smarów plastycznych

Abstract

The article presents the results of research on the influence the type of base oil in lubricating compositions has on the rheological parameters of selected lubricants. Vegetable, mineral, and synthetic dispersion phases were used to produce lubricating greases. The modified amorphous silica was used as the dispersed phase. However, as a modifying additive was used a substance containing the antioxidants, corrosion inhibitors, and EP/AW additives. The experiments on rheological properties were carried out using a Physica MCR 101 rotational rheometer (manufactured by Anton Paar), equipped with a diffusion air bearing and connected to a pneumatic supply – an oil-free Jun-Air compressor and air drying block. The device is equipped with a Peltier system for temperature control in the range of –20°C to 200°C and an external thermostatic VISCOTHERM V2 system, working in the temperature range of –20°C to 200°C. The rheometer control and measurement data analysis were performed using Rheoplus software. The tests were carried out using a cone-plate measuring system with a shear rate range of 0.01–100 s-1 at 20°C for lubricating compositions prepared on various oil bases. To evaluate the value of rheological parameters, the results of tests of the dependence between shear stress and shear rate (flow curves) were used. For the theoretical determined on the flow curves, the following rheological models were used: Bingham, Herschel–Bulkley, Casson, and Tscheuschner. The values of the shear stress (yield point) in depending on the type of dispersion phase has changed. This proves that the use of a base oil with the appropriate functional properties does not weaken, but reinforces the spatial structure of a lubricating grease. It has an important meaning when selecting construction parameters when designing a central lubrication system with grease made from a vegetable oil base (Abyssinian oil). The rheological properties of the lubricating grease are influenced by the type of base oil and thickener, any additives in the grease, the production technology of the grease, and the conditions in which it is used. The tests revealed an important influence of the base oil on the rheological parameters that describe the behaviour of lubricating compositions subjected to stresses and strains in a lubricating system.