Wood sponge with photothermal, magnetically driven, and superhydrophobic characteristics for high-viscosity oil–water separation

Abstract

In this work, naturally degradable porous balsa wood was used as a raw material to prepare a highly elastic wood sponge (WS) substrate using a two-step chemical method and a freeze-drying method. The surface hydrophobic modification of Fe3O4 nanoparticles using the fluorine-free material octadecyltrimethoxysilane (C18TMS) solved the problem of agglomeration caused by the high nanoparticle surface energy. Polydopamine (PDA), hydrophobically modified Fe3O4 (C18TMS/Fe3O4), and low-surface-energy polydimethylsiloxane (PDMS) were sprayed onto WS substrates using a simple spraying method. An environmentally friendly adsorption sponge with photothermal, magnetically driven, and superhydrophobic properties was prepared for the first time using this method. The prepared sponge had a water droplet contact angle of 156.8° and exhibited excellent oil–water separation performances. Due to the addition of PDA and Fe3O4, the modified sponge exhibited excellent photothermal performance, rapidly heating to 63.4°C under a sunlight intensity of 1 kW m−2. The superhydrophobic WS prepared in this experiment provides a more environmentally friendly and low-cost way for high viscosity oil–water separation and targeted removal of oil pollution.