Wood Sponge Reinforced with Polyvinyl Alcohol for Sustainable Oil-Water Separation.

Abstract

The excellent oil absorption capacity and sustainability advantages of adsorbent-type oil-absorbing products have become the primary method to deal with marine oil spills and organic pollution at this stage, especially aerogel products. However, this type of material also has some problems, such as secondary pollution during nanocellulose preparation. Lignin and hemicellulose were removed from the natural wood, and followed by the action of freeze drying, the wood sponge was prepared. Then, followed by immersing the wood sponge into polyvinyl alcohol solution (PVA) and dipping it in polydimethylsiloxane solution, the target PVA-reinforced wood sponge with better mechanical compressibility and hydrophobic properties was obtained. The new wood sponge showed high mechanical compressibility (reversible compression rate of 40%) and elastic recovery rate (the height retention rate was about 100% after 200 cycles of 30% strain). It also showed excellent hydrophobic and oleophilic properties, and the water contact angle was up to 138°, and the oil absorption capacity was 25 g·g–1. The ability of oil absorption can be recovered by compression, and the high absorption rate was maintained after 50 cycles. The wood sponge has great potential in reusable oil–water separation due to low cost, high efficiency, high performance, biodegradability, environmental friendliness, and other advantages.