Abstract

Environmental pollution and energy shortage make the development of clean energy more and more urgent. As a kind of clean renewable energy, hydrogen has attracted more attention recently. WO3-based materials have emerged as one of the most promising candidates for electrocatalytic hydrogen evolution reaction (HER), due to their attractive electrocatalytic activity, low cost as well as the electrochemical durability. In this minireview, we systematically provide an overview of WO3-based materials applied for HER, including pure WO3, the doped WO3 and the WO3-based composite materials. Furthermore, the strategies to enhance their electrocatalytic performance are summarized and discussed, such as morphological engineering, doping, as well as compositing with other materials. Finally, the limitation and challenges of WO3-based materials for HER and their prospects for future research are proposed. We believe that this minireview will be favourable for scientists to seek more promising HER electrocatalysts.

Highlights

  • Nowadays, the discovery and use of fossil fuels have made great contributions to the development of human society

  • Wondimu et al (2018a) developed novel electrocatalyst tungsten oxide NWs with rich O vacancies supported by nitrogen doped-reduced graphene oxide (N-rGO), which exhibits better hydrogen evolution reaction (HER) performance than Fe-WOxP/rGO approaching to Pt/C

  • It is clear that the strategies mentioned above are useful and meaningful for optimizing the electrocatalytic performance of WO3

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Summary

Introduction

The discovery and use of fossil fuels (such as coal and petroleum) have made great contributions to the development of human society Recently, Tian et al (2019) reported unique highly dispersed Pt atom clusters on WO3@CFC (carbon fiber cloth) as superior electrocatalysts for HER. The electrocatalytic performances of WO3 have been greatly enhanced by utilizing nano/micrometer-sized WO3, mainly due to their high surface area to volume ratio.

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