WITHDRAWN: Counterions, smectite, and palygorskite increase microstructural stability of saline-sodic soils

Abstract

Abstract Saline-sodic soils are susceptible to wind and water erosion when the dispersive effect of sodium overcomes inter-particle bonds. Rheological parameters of viscoelasticity can help to quantify inter-particle attractive forces and account for the effect of salinity in these soils. The main objective of the present study was to investigate the viscoelasticity behavior of saline-sodic soils of the Sirjan playa in south-central Iran. Three representative pedons were excavated and described by horizon. Soil physicochemical properties and rheological properties were determined, namely the micromechanical parameters flow point (γf), loss factor tan δ, and integral z, with samples analyzed at three matric potentials (0, −6, and −15 kPa). Results showed that soil microstructural stiffness was mainly influenced by soil texture, clay minerals, gypsum, calcium carbonate equivalent (CCE), and matric potential. The dispersive effect of sodium, as indicated by low integral z and γf values, decreased with increasing gypsum content in − 6 and − 15 kPa matric potentials (0.6 0.8). However, greater microstructural stability (i.e., higher integral z and γf) was observed for fine-textured soils with relatively high amounts of smectite and palygorskite and low pH. Furthermore, integral z and γf increased with lower matric potentials due to the stabilizing effect of menisci forces. Therefore, the viscoelastic behavior of the saline-sodic soils was negatively associated with water content and high sodium concentration, while the presence of smectite, palygorskite, gypsum, and CCE improved the soil physical conditions and thus the rigidity of the porous system. These results demonstrate that rheological measurements can identify saline-sodic soils that have strongly degraded microstructural stability and would most benefit from active management and amelioration.