WITHDRAWN: A combinatorial bioinnovative approach integrating synthetic dye bioremediation and bioenergy production using waste pepper seed biomass

Abstract

A combinatorial study integrating synthetic dye bioremediation and biodiesel production using discarded pepper seed biomass was performed for a cleaner and more sustainable environment/energy in the present work. The vegetal oil was extracted from the pepper seed biomass and the defatted residual biomass was mainly investigated as a sustainable green generation alternative biosorbent source for the treatment of colored aqueous effluents. To test the wastewater cleaning ability of biosorbent, basic red 46 was selected as a common harmful model synthetic dye. The kinetic, equilibrium and thermodynamic modeling studies were performed to elucidate the dye biosorption behavior of biosorbent. Besides, the performance of dye bioremediation system was evaluated using the kinetic modeling parameters, and for large scale dye purification applications, a single-stage batch bioreactor system was designed using the mathematical modeling data. The operating conditions significantly affected the biosorption process. The pseudo-second-order and Freundlich models provided the best fit to the kinetic and isotherm data, respectively. The thermodynamic studies showed that the dye biosorption was a feasible and spontaneous process. The maximum dye biosorption capacity of biosorbent based on Langmuir model was predicted as 82.019 mg g-1. As compared many other biosorbents reported in literature for the same contaminant, this high value revealed a great potential of biosorbent for the dye removal from aqueous medium. Thus, the present study showed that the discarded pepper seed biomass could be employed as a highly efficient as well as cost-effective material for both dye bioremediation and biodiesel production in a sustainable manner.