Widening the Gamut of Structural Colors of Gold via Insulator–Metal Bilayer Coatings

Abstract

Tuning the color of Au has been a longstanding problem in the luxury industry. Conventional approaches, involving Au alloying, compromise purity and demand distinct alloy compositions for each hue. This study demonstrates a lithography‐free method for generating structural colors on a gold surface by adjusting the thickness of titanium dioxide, a high‐index dielectric. While color tuneability is limited if TiO2 is coated directly on the Au surface, a range of vivid colors can be generated if a 50−100 nm thick AuAl2 underlayer is used. AuAl2, an accepted alloy for purple gold, broadens the color gamut, providing a protective coating without diminishing gold purity. The reflectance dip of the bilayer structure exhibits a significant red shift with increasing thickness of the TiO2 layer, allowing diverse colors by TiO2 insulator tuning. Simulation studies corroborate experimental results, affirming that coating a TiO2 layer on the AuAl2 underlayer yields a wide range of colors. This method, based on thin‐film interference, shows promise for widespread use, offering a broad spectrum of structural colors in an industry striving for diverse Au color representation.