Abstract
AbstractNMR linewidth studies of nylon 66 as a function of temperature and applied tensile stress have been conducted. The principal motional transition temperature was found to be shifted to higher temperatures with stress application by 9°C./g./den. At any given temperature, increased stress resulted in an increased linewidth. An attempt was made to correlate the shift in the motional transition temperature with the concept that a segment experiencing motion must do work against the applied tensile stress.
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