Abstract
White light emission phosphors NaLa(PO3)4: Dy3+ were synthesized by a solid-state method. XRD analysis confirmed that all the Dy3+ doped phosphors are single phase. The photoluminescence excitation and emission spectra, concentration effect, decay property, and CIE coordinates were investigated. Strong excitation peaks of NaLa(PO3)4: Dy3+ were found around 350–400nm, which matched well with those of the near-UV LED chips. Under 350nm excitation the NaLa(PO3)4: Dy3+ exhibits intense white emission by combining the two emission peaks at 485nm and 571nm, attributed to the characteristic 4F9/2–6H15/2 and 4F9/2–6H13/2 transitions of Dy3+. The optimum doped concentration of Dy3+ ions is around 6mol% and the critical transfer distance of Dy3+ is calculated as 15.4Å. In addition, the CIE chromaticity coordinates of NaLa(PO3)4: Dy3+ phosphors are (0.2923,0.3359). The results indicate that the NaLa(PO3)4: Dy3+ phosphors have great potential as a single-component white-light-emitting phosphor for UV-light-emitting diodes.
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