Abstract

In prior study by our team, orange-yellow afterglow was observed in Eu2+ and Dy3+ co-doped LiSr4(BO3 )3 phosphor due to the emission from Eu2+ center. In this study, further incorporation of Ce3+into the phosphor lead to the observation of white afterglow due to the mixed result of blue light from Ce3+ and orange-yellow light from Eu2+ centers. Upon ultraviolet excitation, the phosphor displays a spectrum characterized from blue emission of Ce3+ at 462nm and orange-yellow emission of Eu2+ at 632nm. Fine-tuning the concentration of Ce3+ enabled the realization of white luminescence in LiSr4(BO3)3: Eu2+, Ce3+ and Dy3+phosphor with chromaticity coordinates of (0.3979, 0.2939). The photoluminescence intensities of the samples could be modulated by incorporating varying amounts of Ce3+ ions, with a critical quenching concentration identified with 0.16 Ce3+. White afterglow is also observed after the removal of the light illumination due to the existence of suitable electron traps with optimal trap depth created by the co-doped Dy3+. The underlying mechanism proposes that the white afterglow is generated by the mixed lights of blue and orange-yellow that are created by the recombination of heat-released electrons from the trap centers with pre-existing holes in the Ce and Eu emission sites.

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